石油化工2012，Vol.41Issue(6)：658-663,6.
纳米MoS2催化剂的制备及其加氢脱氧性能研究
Preparation of MoS2 Nanocatalysts and Their Hydrodeoxygenation Performances
朱威 1王德志 1吴壮志 1王长龙1
作者信息
- 1. 中南大学材料科学与工程学院,湖南长沙410083
- 折叠
摘要
Abstract
Nano MoS2 catalysts were prepared from a ball-milled mixture of MoO3 and S by mechanical activation and then calcination at 400-800 X. In an atmosphere of Ar for 80 min. The products were characterized by means of BET, XRD, SEM and TEM. The performances of the catalysts in the hydrodeoxygenation of 4-methylphenol were investigated. The results showed that the obtained MoS2 catalysts had low stacking layer structure with a length of 100 nm and a thickness of less 10 nm, high specific surface area(about 83.6 m2/g) and monodispersion. The catalytic activity of the MoS2 prepared at calcinations temperature 500
℃ was the highest and the conversion of 4-methylphenol was 58.2%. The hydrodeoxygenation mainly favored deoxygenation route, but as the calcination temperature of the MoS2 catalysts was heightened, the selectivity to hydrogenation pathway was enhanced gradually.关键词
纳米二硫化钼催化剂/4-甲基苯酚/加氢脱氧Key words
nano molybdenum disulfide catalyst/ 4-methylphenol/ hydrodeoxygenation分类
化学化工引用本文复制引用
朱威,王德志,吴壮志,王长龙..纳米MoS2催化剂的制备及其加氢脱氧性能研究[J].石油化工,2012,41(6):658-663,6.
