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铽-邻氨基苯甲酸-十一烯酸与甲基丙烯酸甲酯共聚物的合成与荧光性能研究

贾虎生 张爱琴 段皓

太原理工大学学报2012,Vol.43Issue(3):254-259,6.
太原理工大学学报2012,Vol.43Issue(3):254-259,6.

铽-邻氨基苯甲酸-十一烯酸与甲基丙烯酸甲酯共聚物的合成与荧光性能研究

Syntheses and Luminescent Properties of the Copolymer of Terbium-o-Aminobenzoic Acid-Undecylenic Acid and Methyl Methacraylate

贾虎生 1张爱琴 2段皓1

作者信息

  • 1. 太原理工大学材料科学与工程学院,太原030024
  • 2. 太原理工大学新材料界面科学与工程教育部重点实验室,太原030024
  • 折叠

摘要

Abstract

The rare earth copolymers containing terbium were synthesized with terbium-o-ami-nobenzoic acid-undecylenic acid and methyl methacraylate.IR and UV-vis spectra indicate that the copolymers exhibited the absorption from polymethylmethacraylate.and also the absorption from the ligand; thermogrovimetric analysis and glass transition temperature measurement suggest that the heat stability of the copolymer was increased in comparison with polymer matrix; fluorescence spectra indicate that the luminescent intensity of the copolymer was increased to 11.53 times that of the complex monomer; regression anaysis suggests that luminescent intensity got enhanced with increase of the complex monomer content,with no fluroscence quenching.

关键词

/高分子/荧光性能/回归分析/浓度猝灭

Key words

terbium/polymer/luminescent properties/regression anaysis/fluroscence quenching

分类

通用工业技术

引用本文复制引用

贾虎生,张爱琴,段皓..铽-邻氨基苯甲酸-十一烯酸与甲基丙烯酸甲酯共聚物的合成与荧光性能研究[J].太原理工大学学报,2012,43(3):254-259,6.

基金项目

国家自然科学基金资助项目(51152001) (51152001)

教育部长江创新团队基金资助项目(IRT0972) (IRT0972)

科技部国际科技合作与交流专项基金资助项目(2011DFA52290) (2011DFA52290)

山西省研究生优秀创新基金项目(20103023) (20103023)

太原理工大学学报

OA北大核心CSTPCD

1007-9432

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