太原理工大学学报2012,Vol.43Issue(3):254-259,6.
铽-邻氨基苯甲酸-十一烯酸与甲基丙烯酸甲酯共聚物的合成与荧光性能研究
Syntheses and Luminescent Properties of the Copolymer of Terbium-o-Aminobenzoic Acid-Undecylenic Acid and Methyl Methacraylate
摘要
Abstract
The rare earth copolymers containing terbium were synthesized with terbium-o-ami-nobenzoic acid-undecylenic acid and methyl methacraylate.IR and UV-vis spectra indicate that the copolymers exhibited the absorption from polymethylmethacraylate.and also the absorption from the ligand; thermogrovimetric analysis and glass transition temperature measurement suggest that the heat stability of the copolymer was increased in comparison with polymer matrix; fluorescence spectra indicate that the luminescent intensity of the copolymer was increased to 11.53 times that of the complex monomer; regression anaysis suggests that luminescent intensity got enhanced with increase of the complex monomer content,with no fluroscence quenching.关键词
铽/高分子/荧光性能/回归分析/浓度猝灭Key words
terbium/polymer/luminescent properties/regression anaysis/fluroscence quenching分类
通用工业技术引用本文复制引用
贾虎生,张爱琴,段皓..铽-邻氨基苯甲酸-十一烯酸与甲基丙烯酸甲酯共聚物的合成与荧光性能研究[J].太原理工大学学报,2012,43(3):254-259,6.基金项目
国家自然科学基金资助项目(51152001) (51152001)
教育部长江创新团队基金资助项目(IRT0972) (IRT0972)
科技部国际科技合作与交流专项基金资助项目(2011DFA52290) (2011DFA52290)
山西省研究生优秀创新基金项目(20103023) (20103023)