无机材料学报2012，Vol.27Issue(5)：507-512,6.DOI:10.3724/SP.J.1077.2012.00507
PZT陶瓷粉体的水热合成
PZT Powders Synthesized by Hydrothermal Method
摘要
Abstract
Lead zirconate titanate (PZT) powders with single-phase, cubic morphology and average size of 1 μm were synthesized using hydrothermal methods. Effects of KOH concentration, hydrothermal treatment time and Pb excess were investigated. The results show that KOH concentration has an important influence on the solid solubility of Pb ion in A-site of PZT perovskite structure. The concentration of Pb2+ vacancies increased with the increase of OH- concentration. However, this kind of deficiency could be compensated by adding more Pb ions in the raw materials, and more Pb ions were needed to add with higher alkaline concentration in the starting solution. But excessive compensation of Pb ions would result in the appearance of the second phase.关键词
PZT粉体/水热合成/铅过量Key words
PZT powder/ hydrothermal syntheses/ Pb excess分类
矿业与冶金引用本文复制引用
朱孔军,朱仁强,董娜娜,顾洪汇,裘进浩,季宏丽..PZT陶瓷粉体的水热合成[J].无机材料学报,2012,27(5):507-512,6.基金项目
国家自然科学基金(51172108) （51172108）
航空科学基金(2009ZF52058) （2009ZF52058）
教育部新世纪优秀人才支持计划(NCET-10-0070),长江学者创新团队项目(IRT0968) （NCET-10-0070）
江苏高校优势学科建设工程资助项目 （）
