物理学报2012,Vol.61Issue(15):323-330,8.
介孔二氧化硅基导电聚合物复合材料热导率的实验研究
Thermal conductivity measurements on PANI/SBA-15 and PPy/SBA-15
摘要
Abstract
Conductive polymers polyaniline(PANI) and polypyrrole(PPy) loaded mesoporous silica(SBA-15) composites are prepared and characterized.The one-dimensional reference bar method and the relevant devices to measure the thermal conductivity are introduced and established.The equivalent pore diameter is proposed to characterize the mesostructures of conductive polymers polyaniline(PANI) and polypyrrole(PPy) in PANI/SBA-15 and PPy/SBA-15 composites.The effects of the equivalent and the measurement pore diameters on thermal conductivities of PANI/SBA-15 and PPy/SBA-15 composites are analyzed.The result shows that thermal conductivities of PANI/SBA-15 and PPy/SBA-15 are higher than that of the substrate SBA-15;the thermal conductivity of PANI/SBA-15 is higher than that of PPy/SBA-15;loading of PANI and PPy in pores of PANI/SBA-15 and PPy/SBA-15 composites is more effective than loading outside of pores for improving the thermal conductivities of PANI/SBA-15 and PPy/SBA-15 composites.关键词
介孔二氧化硅复合材料/热导率/聚苯胺/聚吡咯Key words
silica mesoporous composite/thermal conductivity/polyaniline/polypyrrole分类
化学化工引用本文复制引用
黄丛亮,冯妍卉,张欣欣,李威,杨穆,李静,王戈..介孔二氧化硅基导电聚合物复合材料热导率的实验研究[J].物理学报,2012,61(15):323-330,8.基金项目
国家自然科学基金重点项目 ()
霍英东教育基金资助的课题 ()