物理学报2012,Vol.61Issue(16):482-487,6.
染料敏化太阳电池内部光路折转对电子传输特性的影响
Effect of light path folding on the properties of electron transport in dyesensitized solar cell
摘要
Abstract
In this paper, an electron continuity equation with light path folding is developed based on the reflection structure of photoanode in a dye sensitized solar cell (DSC). The characteristics of modulated photocurrent frequency response are calculated, and the effects of light path folding on electron transport property are studied under different absorption and reflection conditions. Intensity modulated photoeurrent spectroscopy measurements show that the established model reflectes the actual characteristic of the response to modulated photocurrent frequency when the light path is folded inside the DSC. The kinetic of electron transfer process depends on the light absorption coefficient, film thickness and large particle reflection ability and other factors in DSC with reflector structure. The deep trap is filled and residence time of electron in trap is shortened. It is attributed to the fact that the light path folding reduces the effect of trap/detrap and accelerates the electron transportation.关键词
染料敏化/太阳电池/光路折转/电子传输Key words
dye sensitized/solar cell/light path folding/electron transport分类
化学化工引用本文复制引用
刘伟庆,寇东星,胡林华,戴松元..染料敏化太阳电池内部光路折转对电子传输特性的影响[J].物理学报,2012,61(16):482-487,6.基金项目
国家重点基础研究发展计划(批准号:2011CBA00700)、国家高技术研究发展计划(批准号:2009AA050603)、中国科学院知识创新工程重要方向项目(批准号:KGCX2-YW-326)和中国博士后科学基金(批准号:20110490835)资助的课题. ()