应用化学2012，Vol.29Issue(8)：906-909,4.DOI:10.3724/SP.J.1095.2012.00379
p-全氟壬烯氧基苯磺酸聚乙二醇酯表面活性剂的合成及表面活性
Synthesis and Performance of Polyethylene Glycol p-Perfluorous Nonenyloxyphenyl Sulflonate Surfactant
摘要
Abstract
Polyethylene glycol p-perfluorous nonenyloxyphenyl sulflonates (PFNPS-PEG-n) were synthesized from p-perfluorous nonenyloxyphenylsulfonyl chloride(PFNPSC) and polyethylene glycol (PEG-n), and were characterized by IR and 19F NMR, respectively. The effects of average relative molecular mass of PEG-n and reaction time on alcoholysis were investigated. The performances of these surfactants such as surface tensions, foaming characterisitics and emulsifiabilities were studied. The surface activity of PFNPS-PEG-n synthesized from PEG-600 is the best, and the optimal reaction conditions are n( PFNPSC):n( PEG-600) = 1:1, reacts at 40 ℃ for 6 ~ 8 h in CC14 in the present of NEt3. The critical micelle concentration (CMC) of PFNPS-PEG-600 is 0. 56 g/L, and its γ CMC is 19. 1 mN/m; 20 mL 1 g/L PFNPS-PEG-600 will produce 95 mL foam, and its half-life time is 75 s. Emulsifiability of PFNPS-PEG-1000 is the best among PFNPS-PEG-n.关键词
氟碳表面活性剂/表面张力/泡沫性能/乳化性能Key words
fluorocarbon surfactant, surface tensions, foaming characterisitics, emulsifiability分类
化学化工引用本文复制引用
赵琴琴,史鸿鑫,武宏科,陈立军,项菊萍..p-全氟壬烯氧基苯磺酸聚乙二醇酯表面活性剂的合成及表面活性[J].应用化学,2012,29(8):906-909,4.基金项目
浙江省科技厅创新团队资助项目(2011R09002-10) （2011R09002-10）
