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玻璃纤维增强PA66复合材料非等温结晶动力学的研究

陈坤 郑梯和 周志诚 宋克东 曹喆

中国塑料Issue(8):31-34,4.
中国塑料Issue(8):31-34,4.

玻璃纤维增强PA66复合材料非等温结晶动力学的研究

Study on Nonisothermal Crystallization Kinetics of Glass Fiber Reinforced PA66 Composites

陈坤 1郑梯和 1周志诚 1宋克东 1曹喆1

作者信息

  • 1. 株洲时代新材料科技股份有限公司,湖南株洲412007
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摘要

Abstract

The crystallization behavior of glass fiber reinforced PA66 composites was characterized using DSC. Parameters of isothermal and non-isothermal crystallization kinetics were calculated using of Mo and Kissinger methods. It showed that glass fiber played as a heterogeneous nucleating agent, which increased the crystallization rate of PA66. When the glass fiber content was 30 %, the crystallization rate reached the maximum. The greater the cooling rate, the greater the degree of crystallinity. The crystallization activation energy of the composites were -297. 22, -356. 32, -481. 00, and -365. 59 kJ/mol, respectively, when the glass fiber contents were 0, 15%, 30 %, and 45%.

关键词

聚酰胺66/玻璃纤维/复合材料/非等温结晶动力学

Key words

polyamide 663 glass fiber/composite/nonisothermal crystallization kinetics

分类

化学化工

引用本文复制引用

陈坤,郑梯和,周志诚,宋克东,曹喆..玻璃纤维增强PA66复合材料非等温结晶动力学的研究[J].中国塑料,2012,(8):31-34,4.

中国塑料

OA北大核心CSCDCSTPCD

1001-9278

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