安徽大学学报（自然科学版）2012，Vol.36Issue(5)：92-96,5.
可聚合乳化剂在丙烯酸酯乳液聚合中的应用研究
Applied research of polymerizable emulsifier in acrylic emulsion polymerization
摘要
Abstract
Polyacrylate emulsions were synthesized by seeding semi-continuous emulsion polymerization with the polymerizable emulsifier ammonium sulfate allyoxy nonylphonoxy poly ( ethyleneoxy) (10) ether (DNS -86). Effects of the type of surfactants, the amount of DNS-86, the amount of initiator and reactive temperature on the properties of the emulsion and films were discussed. The structure and morphology of products were characterized by FT-IR and TEM, obtaining the best synthesis condition. The results showed that the conversion rate of monomers was increased and polymerization stability was effectively improved by using polymerizable emulsifier DNS-86. The mechanical properties and water resistance of films were markedly improved with the increase of DNS-86 amount.关键词
可聚合乳化剂/丙烯酸酯/乳液聚合Key words
polymerizable emulsifier/ acrylate/ emulsion polymerization分类
化学化工引用本文复制引用
吕俊,汪丽娟,聂王焰,周艺峰,宋林勇..可聚合乳化剂在丙烯酸酯乳液聚合中的应用研究[J].安徽大学学报（自然科学版）,2012,36(5):92-96,5.基金项目
安徽省绿色高分子材料重点实验室开放课题基金资助项目(KF2011006) （KF2011006）
安徽大学博士科研启动经费资助项目 （）
安徽大学“211工程”三期建设学术创新团队经费资助项目 （）
