爆破器材2012，Vol.41Issue(4)：9-11,15,4.
N2O5/HNO3体系硝解三(N-乙酰基)六氢化均三嗪制备RDX
Preparation of RDX by Nitrolysis of 1,3,5-Triacetyl Hexahydro-1,3,5-Triazaine with N2O5/HNO3
摘要
Abstract
1,3,5-Triacetyl hexahydro-1,3,5-triazaine (TRAT) was prepared from acetonitrile and 1,3,5-trioxane in the presence of sulfuric acid as catalyst according to a literature process, and TRAT was then nitrated with N2O5/HNO3 as nitrating agent to RDX Experiment results showed that when the reaction temperature was 50℃ , reaction time lh and molar ratio of n(N2O3) : n(HNO3) : n(TRAT) =6 : 60 : 1, the yield of the RDX was up to 87.4%. The structure of the compound was characterized by NMR and IR. The main side product was researched and confirmed by MS.关键词
N2O5/RDX/硝解/炸药Key words
N2O3, RDX , nitration, explosive分类
军事科技引用本文复制引用
张袁斌,陈文靖,叶志文..N2O5/HNO3体系硝解三(N-乙酰基)六氢化均三嗪制备RDX[J].爆破器材,2012,41(4):9-11,15,4.基金项目
国家大学生创新创业训练计划(njust016) （njust016）
