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C/SiC复合材料的低温制备工艺研究

周长城 张长瑞 胡海峰 张玉娣

材料工程Issue(9):44-47,4.
材料工程Issue(9):44-47,4.

C/SiC复合材料的低温制备工艺研究

Preparation of C/SiC Composites at Low Temperature

周长城 1张长瑞 2胡海峰 2张玉娣2

作者信息

  • 1. 总后建筑工程研究所,西安710032
  • 2. 国防科学技术大学航天与材料工程学院,长沙410073
  • 折叠

摘要

Abstract

In order to introduce actively cooling technology into ceramic matrix composites, it is essential to decrease the preparation temperature of ceramic matrix composites. The conversion process of the polycarbosilane (PCS) into silicon carbide (SiC) was investigated by TG-DTA, infrared spectrum analysis (IR) and X-ray diffraction (XRD) etc, which indicated the feasibility of transition from PCS to SiC ceramic at low temperatures under 1000°C. The carbon fiber reinforced silicon carbide (C/SiC) composites were hereby prepared at low temperatures as 900℃ through precursor infiltration and py-rolysis (PIP), and polycarbosilane (PCS) acted as precursor, carbon fiber as enhanced fiber. The results show that the mechanical properties of C/SiC composites prepared at 900℃ are excellent, flexur-al strength of composites prepared at 900℃ reaching 657. 8MPa, shear strength 61. 02MPa, fracture toughness 22. 53MPa · m1'2 , and density being only 1. 70g/cm\ Furthermore, the fracture surface was analyzed by SEM.

关键词

PCS/C/SiC/复合材料/先驱体浸渍裂解/低温制备

Key words

PCS/C/SiC/composite/PIP/low temperature pyrolysis

引用本文复制引用

周长城,张长瑞,胡海峰,张玉娣..C/SiC复合材料的低温制备工艺研究[J].材料工程,2012,(9):44-47,4.

材料工程

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