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水热法制备Mo掺杂WO3纳米材料及其光致变色性质的研究

周妍 张然 王东生 杨斌

材料工程Issue(10):73-79,83,8.
材料工程Issue(10):73-79,83,8.

水热法制备Mo掺杂WO3纳米材料及其光致变色性质的研究

Hydrothermal Synthesis and Photochromic Characterization of Mo Doped WO3 Nanomaterial

周妍 1张然 2王东生 1杨斌1

作者信息

  • 1. 铜陵学院机械工程系,安徽铜陵244000
  • 2. 铜陵学院信息管理与系统工程研究所,安徽铜陵244000
  • 折叠

摘要

Abstract

WO3 is a multi-functional semiconductor, and photochromism is one of the most important characterizations WO3 owns. This work has established a facile method to synthesize Mo doped hexagonal WO3 using W powder, Mo powder and hydrogen peroxide as starting agents and adding Na2SO4 as a mineralizer. The morphology, size, phase structure and component were characterized by applying SEM, XRD, HRTEM, XPS, etc, and it is confirmed that Mo is successfully doped into WO3 as MoxW1-xO3. After irradiated with Xe lamp, the novel MOx-W1-xO3 material holds much better photo-chromic phenomenon than pure WO3. The involved smaller band gap resulted in the more electron produce after irradiation. Moreover, by doping Mo, the electron transfer in this special structure is highly enhanced.

关键词

WO3纳米材料/掺杂/光致变色/水热法

Key words

WO3 nanomaterial/doped/photochromism/hydrothermal

分类

通用工业技术

引用本文复制引用

周妍,张然,王东生,杨斌..水热法制备Mo掺杂WO3纳米材料及其光致变色性质的研究[J].材料工程,2012,(10):73-79,83,8.

基金项目

安徽省教育厅高校自然科学研究项目(KJ2010B233 ()

KJ2010B234) ()

材料工程

OA北大核心CSCDCSTPCD

1001-4381

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