河北科技大学学报2012，Vol.33Issue(4)：300-304,5.
咪唑类离子液体的微波水浴合成及性能研究
Study on microwave-assisted synthesis and performance of imidazole ionic liquids
摘要
Abstract
Two kinds of imidazole ionic liquids([BM1M]PF6 and [BMIM]BF4) are synthesized from N-methyl-midazolium, chlorobutane, KPF6 and NaBF4 under microwave irradiation and water bath heating respectively by two-step method. The advantage and disadvantage in the synthesis of intermediate and anion exchange are compared, and the structure characteristics and electrochemical performance are characterized. The result shows that the ionic liquids synthesized by two different methods have no evident discrepancy. The reaction time can be cut down markedly under the microwave, and the productivity can exceed 90% , while the water bath heating is propitious to anion exchange. So combining the two methods will get a favorable result.关键词
咪唑离子液体/微波合成/性能表征Key words
imidazole ionic liquid/ microwave irradiation synthesis/ performance characterization分类
化学化工引用本文复制引用
李昌家,李景印,李娜,郭玉凤,刘方方..咪唑类离子液体的微波水浴合成及性能研究[J].河北科技大学学报,2012,33(4):300-304,5.基金项目
河北省科技支撑计划项目(11215114D) （11215114D）
河北科技大学校立科研基金资助项目(XL200908) （XL200908）
