河北化工2012,Vol.35Issue(10):42-44,3.
2-巯基吡啶与Cu(I)配合物的合成、晶体结构及光物理性质
Synthesis,Crystal Structure and Photophysical Property of the Complex of 2-Mercaptopridine with Cu(I)
摘要
Abstract
A new Cu(I) complex { [Cu3 (py2tH) 6 (BF4) 3 · H2 O}, was synthesized from [Cu(CH3 CN) 4 ]BF4,2-mercaptopridine and phenanthroline. The structure of the complex was determined by X-ray diffraction single crystal. The photophysical property was obtained from the analysis of the modern spectroscopic methods. The emission peak at 632 nm belongs to metal to ligand charge transition(MLCT).关键词
Cu(I)配合物/合成/晶体结构/光物理性质Key words
Cu (I) complex/synthesis/crystal structure/photophysical property分类
化学化工引用本文复制引用
于玲..2-巯基吡啶与Cu(I)配合物的合成、晶体结构及光物理性质[J].河北化工,2012,35(10):42-44,3.基金项目
邢台学院2011年科研立项校级课题(编号:XTXY11Y11). ()