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高温液态水条件下木糖直接转化制备糠醛的工艺

孙啸寅 党杰 华德润 李盼盼 吴玉龙 杨明德 李春

化工进展2012,Vol.31Issue(9):1942-1945,1958,5.
化工进展2012,Vol.31Issue(9):1942-1945,1958,5.

高温液态水条件下木糖直接转化制备糠醛的工艺

Research on direct conversion of xylose to furfural in high temperature water

孙啸寅 1党杰 2华德润 2李盼盼 2吴玉龙 2杨明德 2李春3

作者信息

  • 1. 石河子大学化学化工学院,新疆石河子832003
  • 2. 清华大学核能与新能源技术研究院,北京100084
  • 3. 石河子大学化学化工学院,新疆石河子832003 北京理工大学生命学院,北京100081
  • 折叠

摘要

Abstract

Direct conversion of xylose into furfural in high-temperature water(HTW) was carried out in a self-made high-pressure reactor.The effect of HTW as the reaction medium on xylose conversion and furfural yield was investigated,and was compared with others catalyst used in the literature.The effects of different solvents on the extraction of furfural were studied.The result showed that HTW was a perfect catalyst medium,which could replace liquid acid and solid acid in the conversion of xylose into furfural.The optimal furfural yield of 78% was obtained at a reaction temperature of 200 ℃,a holding time of 3 h and initial xylose concentration of 10%.In addition,furfural could be well extracted by n-butyl acetate.Therefore,a novel approach to furfural production is presented,providing a basis as well as technical parameters for its commercialization.

关键词

木糖/糠醛/高温液态水/萃取/直接转化

Key words

xylose/furfural/high-temperature water(HTW)/extraction/direct conversion

分类

化学化工

引用本文复制引用

孙啸寅,党杰,华德润,李盼盼,吴玉龙,杨明德,李春..高温液态水条件下木糖直接转化制备糠醛的工艺[J].化工进展,2012,31(9):1942-1945,1958,5.

基金项目

国家973计划 ()

国家自然科学基金(21176142)项目 ()

化工进展

OA北大核心CSCDCSTPCD

1000-6613

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