化工进展2012，Vol.31Issue(10)：2282-2287,6.
基于RAFT聚合策略合成功能化聚烯烃嵌段聚合物的研究进展
Progress of synthesis of functional polyolefin block copolymers via strategy based on RAFT polymerization
摘要
Abstract
The paper briefly describes the general polymerization mechanism of reversible addition-fragmentation chain transfer(RAFT) polymerization and some common RAFT agents.The RAFT polymerization is compared with other two kinds of active controlled radical polymerizations [nitrogen oxide mediated free radical polymerization(NMP) and atom transfer radical polymerization(ATRP)].The recent progress of synthesis of functional polyolefin block copolymers on the basis of RAFT polymerization is reviewed.Six kinds of combined methodologies based on RAFT polymerization aiming at the synthesis of functional polyolefin block copolymers are introduced:① Combination of olefin coordination polymerization and RAFT polymerization,②Combination of living anionic polymerization and RAFT polymerization,③Combination of cationic polymerization and RAFT polymerization,④ Combination of Click chemistry and RAFT polymerization,⑤ Combination of ring-opening polymerization and RAFT polymerization,⑥Combination of living polymerization of Ylides and RAFT polymerization.Finally,the prospect of the design and synthesis of functional polyolefin block copolymers via the strategy based on RAFT polymerization is presented.关键词
可逆加成-断裂链转移聚合/功能化聚烯烃/嵌段聚合物Key words
reversible addition-fragmentation chain transfer polymerization(RAFT)/functional polyolefin/block copolymers分类
化学化工引用本文复制引用
毛国梁,王欣,宁英男,马志..基于RAFT聚合策略合成功能化聚烯烃嵌段聚合物的研究进展[J].化工进展,2012,31(10):2282-2287,6.基金项目
国家自然科学基金 （）
黑龙江省留学归国人员科学基金 （）
黑龙江省教育厅海外学人科研资助（1154H14）项目 （）
