化工进展2012,Vol.31Issue(11):2493-2510,18.
纳米结构多孔固体在二氧化碳吸附分离中的应用
Nanostructured porous solids for CO_2 sorption and separation
摘要
Abstract
Due to the dual roles of CO2 as a main greenhouse gas and a renewable C1 carbon source,research on CO2 adsorption and separation is of great importance to both academic interests,and social and economic progresses.Based on various kinds of porous materials with distinct structural parameters,this paper reviews the recent development of novel porous CO2 sorbents and their sorption behavior.Porous carbons possess controllable micro/macroscopic morphology,tunable pore structure and good stability.Molecular sieves have rich microporosity with concentrated pore size distribution.Metal-organic frameworks and porous polymers offer a great variety of products,representing newly emerging CO2 capture materials.In addition,key issues on structure effect of new sorbents on high efficiency CO2 capture under actual conditions are discussed.Finally,perspectives on how to design the composite and the quantitative analysis of pore structure contributing to sorption capacity are provided.关键词
多孔固体/吸附法/纳米结构/二氧化碳/吸附分离Key words
porous solids/adsorption process/nanostructure/carbon dioxide/sorption and separation分类
化学化工引用本文复制引用
郝广平,李文翠,陆安慧..纳米结构多孔固体在二氧化碳吸附分离中的应用[J].化工进展,2012,31(11):2493-2510,18.基金项目
教育部“新世纪优秀人才支持计划” ()
博士点基金 ()
中央高校基本科研业务费 ()
教育部留学回国人员科研启动基金项目 ()