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磁性LDH负铜催化剂的制备及其对直接青莲D-BL的脱色

刘琰 李剑超 张红 刘啸乾 杨晓青 毛勇

环境工程学报2012,Vol.6Issue(10):3417-3423,7.
环境工程学报2012,Vol.6Issue(10):3417-3423,7.

磁性LDH负铜催化剂的制备及其对直接青莲D-BL的脱色

Synthesis and evaluation of copper-loaded magnetic LDH catalysts used in decoloration of dyestuff D-BL

刘琰 1李剑超 2张红 2刘啸乾 2杨晓青 3毛勇2

作者信息

  • 1. 陕西师范大学环境科学系,西安710062 山东海美侬项目咨询有限公司,济南250100
  • 2. 陕西师范大学环境科学系,西安710062
  • 3. 山东海美侬项目咨询有限公司,济南250100
  • 折叠

摘要

Abstract

The magnetic particles of Fe3O4 were coated by Mg-Al layered double hydroxides via co-precipitation firstly.With anion exchange reactions,the coordination compound [Cu(C2O4)2]-was intercalated into the layers of the magnetic LDHs,and the prepared solids were calcined to obtain inorganic CCML catalysis(copper-loaded magnetic LDH catalysts).The catalysts were characterized via SEM,X-Ray,FT-IR.And the catalysis performance of them was evaluated with a set of static experiments.Optimum conditions of preparation were that the magnetic LDHs were modified by [Cu(C2O4)2]-solution for one time,the temperature and time of calcination were 450℃ and 5 h,respectively.In the static CWPO experiments of decoloration of direct violet D-BL,CCML catalysts can obtain removal rates of 99.62%,90.43% and 81.92% with original dye concentrations of 200,300 and 500 mg/L,respectively.

关键词

LDH/焙烧/催化/染料废水/CWPO

Key words

LDH/calcination/catalytic/dye wastewater/CWPO

分类

资源环境

引用本文复制引用

刘琰,李剑超,张红,刘啸乾,杨晓青,毛勇..磁性LDH负铜催化剂的制备及其对直接青莲D-BL的脱色[J].环境工程学报,2012,6(10):3417-3423,7.

基金项目

国家自然科学基金资助项目 ()

教育部留学回国人员科研启动基金 ()

陕西省攻关计划项目 ()

环境工程学报

OA北大核心CSCDCSTPCD

1673-9108

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