华侨大学学报（自然科学版）2012，Vol.33Issue(5)：518-521,4.
2,3,6,7-四甲基三蝶烯的新型有效合成及表征
New Efficient Synthesis and Characterization of 2,3,6,7-Tetramethyltriptycene
摘要
Abstract
Oxylene and benzyl alcohol underwent friedel-crafts alkylation reaction with anhydrous aluminum chloride as catalyst, by way of carbonium ion mechanism to afford 2,3,6,7-tetramethylanthracene. Then, 2,3,6,7-tetramethylan- thracene and benzyne generated in situ underwent a Diels-Alder reaction to give 2,3,6,7-tetramethyltriptycene containing an unique three-dimensional rigid aromatic structure. Finally, the structures of 2,3,6,7-tetramethylanthracene and 2,3, 6,7-tetramethyltriptycene were characterized by IR and ' H NMR spectroscopy.关键词
2,3,6,7-四甲基蒽/2,3,6,7-四甲基三蝶烯/Diels-Alder反应/苯甲醇/邻二甲苯Key words
2,3,6,7-tetramethylanthracene/ 2,3,6,7-tetramethyltriptycene/ Diels-Alder reaction/ benzyl alcohol/ o-xy-lene分类
化学化工引用本文复制引用
刘嘉川,程琳..2,3,6,7-四甲基三蝶烯的新型有效合成及表征[J].华侨大学学报（自然科学版）,2012,33(5):518-521,4.基金项目
国家自然科学基金资助项目(50673031,50973036) （50673031,50973036）
