化学工程2012，Vol.40Issue(8)：29-32,4.DOI:10.3969/j.issn.1005-9954.2012.08.007
甲醇氧化羰基化合成碳酸二甲酯催化剂研究进展
Advances in catalyst for synthesis of dimethyl carbonate by oxidative carbonylation of methanol
摘要
Abstract
There are several methods for the synthesis of dimethyl carbonate, especially, the oxidative carbonylation of methanol has an attractive industrial prospects due to its features of low erosion, relatively easier separation of products, attainable raw materials, etc. The structural features and catalytic performances of Co, Pd, Cu and Au systems were introduced and compared in the oxidative carbonylation of methanol to dimethyl carbonate. In order to promote the catalytic performance and selectivity of the catalyst, extending its life and reducing its corrosion, the reaction mechanism should be further studied, and the effective catalyst promoters and catalyst carriers should be added. The halogen-free copper catalysts are the important research direction for the carbonylation synthesis of dimethyl carbonate.关键词
碳酸二甲酯/甲醇/氧化羰基化/催化剂Key words
dimethyl carbonate/ methanol/ oxidative carbonylation/ catalyst分类
化学化工引用本文复制引用
杜治平,周彬,熊剑,黄丽明,黄晨,林志坤,吴元欣..甲醇氧化羰基化合成碳酸二甲酯催化剂研究进展[J].化学工程,2012,40(8):29-32,4.基金项目
国家自然科学基金重点资助项目(20936003) （20936003）
湖北省自然科学基金重点资助项目(2008CDA009) （2008CDA009）
湖北省教育厅科学技术研究项目(Q20101511) （Q20101511）
