南京工业大学学报（自然科学版）2012，Vol.34Issue(5)：22-25,4.DOI:10.3969/j.issn.1671-7627.2012.05.005
PMMA-PLA-PMMA三嵌段共聚物的制备
Synthesis of poly ( methyl methacrylate ) -poly ( lactic acid) -poly (methyl methacrylate) tri-block copolymer
摘要
Abstract
Poly( methyl methacrylate)-poly (lactic acid)-poly ( methyl methacrylate) tri-block copolymer was prepared using bromize poly ( lactic acid) as the initiator via atom transfer radical polymerization (ATRP). The effects of n( MMA)/n( Br-PLA-Br) on molecular weight were investigated. Results showed that the first-order plot and a narrow molecular weight distribution followed the characteristics of the ATRP , indicating a controllable polymerization. The glass transition temperature and initial decomposition temperature of the copolymer were well improved by copolymerization, thus it had a potential application in plastic industry.关键词
原子转移自由基聚合/聚甲基丙烯酸甲酯/聚乳酸Key words
atom transfer radical polymerization/ poly (methyl methacrylate) / poly (lactic acid)分类
通用工业技术引用本文复制引用
沈珺,仲玉,魏荣卿,刘迎,刘晓宁,江伟,薛奇..PMMA-PLA-PMMA三嵌段共聚物的制备[J].南京工业大学学报（自然科学版）,2012,34(5):22-25,4.基金项目
国家高技术研究发展计划(863计划)资助项目(2007AA02Z200,2007AA06A402) （863计划）
