皮革科学与工程2012，Vol.22Issue(4)：5-10,6.
长链烃基改性硅油PMHS-g-LCAA的合成与结构表征
The Synthesis and Structural Characterization of Polymethylhydrosiloxane Grafted with Long Chain Alcohol Acrylate Functional Group
摘要
Abstract
Long chain alcohol acrylate was grafted to polymethylhydrosiloxane bone by hydrosilylation, with hexachloroplatini acid as catalyst. Through orthogonal experiment, main factors affecting the graft reaction between LCAA and PMHS were discussed. FTIR and 1H-NMR spectra indicated that the hydrosilylation reaction followed the Markovnikov' s rule and played a strong preference toward β -1, 2 - addition.关键词
聚甲基氢硅氧烷/丙烯酸高碳醇酯/硅氢加成反应/长链烃基改性硅油Key words
Polymethylhydrosiloxane/long chain alcohol acrylate/ hydrosilylation/ LCAA modified silicone oil.分类
轻工纺织引用本文复制引用
宋秘钊,赵欣,张景彬,孙晓泉..长链烃基改性硅油PMHS-g-LCAA的合成与结构表征[J].皮革科学与工程,2012,22(4):5-10,6.基金项目
黑龙江省人事厅博士后课题(407302)和黑龙江省教育厅青年骨干课题(015205) （407302）
