沈阳大学学报：自然科学版2012，Vol.24Issue(5)：15-18,4.
基于多金属钼氧酸盐阴离子构筑的配合物[Zn（bpy）Mo3O（10）]的合成及晶体结构
Hydrothermal Synthesis and Crystal Structure of Complex [Zn(bpy)Mo_3O_(10)] Constructed by Molybdenium Oxide Anions
摘要
Abstract
A new layered complex [Zn(bpy)Mo3O10] 1 containing ladder-like molybdenium oxide anion clusters was synthesized under hydrothermal conditions.It was determined structurally by X-ray single crystal diffraction and characterized by elemental analysis,IR spectroscopy and TG analysis.The supporting {Mo3O10}2-anion exhibits an infinite 1D ribbon structure and constructed by {MOO6} Octahedra,{MOO5} square pyramid and{MOO4} tetrehedra,and then the ribbons were connected through {Zn(bpy)}2+ fragments into a 2D layer structure.关键词
钼氧酸盐/锌配合物/单晶结构/水热合成Key words
molybdate/Zn Complex/single crystal Structure/hydrothermal synthesis分类
数理科学引用本文复制引用
胡天慧,由万胜..基于多金属钼氧酸盐阴离子构筑的配合物[Zn（bpy）Mo3O（10）]的合成及晶体结构[J].沈阳大学学报：自然科学版,2012,24(5):15-18,4.基金项目
国家自然科学基金资助项目 （）
