天然气化工2012，Vol.37Issue(4)：11-14,18,5.
表面活性剂用量对完全液相法制备的Cu-Zn-Al合成醇催化剂性能影响
Effect of surfactant dosage on the performance of Cu-Zn-Al catalyst prepared by complete liquid-phase technology for alcohol synthesis
摘要
Abstract
Cu-Zn-Al slurry catalysts were prepared by a complete liquid-phase technology and characterized by XRD, H2-TPR and NH3-TPD. The effect of dosage of the surfactant polyvinylpyrrolidone(PVP)used for catalyst preparation on the performance of catalysts in synthesis of higher alcohols from syngas was investigated. The results showed that increasing PVP amount could improve selectivity of C2+ alcohols and reduce methanol formation. PVP amount affected Cu° particle size of the catalysts, which was closely related to selectivity of alcohols. The smaller the Cu° particle size was, the higher the selectivity of methanol was. The larger the Cu° particle size was, the higher the selectivity of C2+ alcohols was.关键词
铜锌铝催化剂/完全液相制备法/低碳醇/合成/合成气/表面活性剂/PVPKey words
Cu-Zn-Al catalyst/complete liquid-phase technology/higher alcohols/synthesis/syngas/surfactant/PVP分类
化学化工引用本文复制引用
延静,李文辉,黄伟..表面活性剂用量对完全液相法制备的Cu-Zn-Al合成醇催化剂性能影响[J].天然气化工,2012,37(4):11-14,18,5.基金项目
国家自然科学基金(20471040),国家重点基础研究发展计划(973计划)(2005CB221204) （20471040）
