物理学报2012,Vol.61Issue(17):553-558,6.
利用色彩转换法制备高色稳定性的柔性白色有机电致发光器件
Highly color-stability flexible white organic light-emitting devices fabricated by color conversion method
摘要
Abstract
We demonstrate flexible white organic light-emitting diode (WOLED) with high color stability, which combines vacuum deposited blue flexible organic light-emitting diode (FOLED) with red surface color conversion material (CCM). Firstly, we utilize the novel multiple quantum well (MQW), which consists of the alternate layers of 2, 3, 5, 6-Tetrafluoro-7, 7, 8, 8-tetracyano-quinodimethane (F4-TCNQ) and 4, 4′, 4″-tris-(N-3-methylphenyl-N-phenylamino) tripheny-lamine (m-MTDATA) as hole injection layer (HIL), through combining a new blue emitting material of N^6, N^6, N^12, N^12-tetrap-tolylchrysene-6, 12-diamine (NCA), to fabricate highly efficient blue FOLED. Then, the CCM of 4-(dicyanomethylene)-2-tert-butyl-6-(1, 1, 7, 7-tetramethyljul-oli-dyl-9-en-yl)-4H-pyran (DCJTB) is deposited on the outside of the ITO flexible substrate. Finally, the thickness of the color conversion film (CCF) is optimized to improve the color purity of flexible WOLED. The results demonstrate that at a driving voltage of 7 V, the CIE coordinates of (0.33, 0.27) which are very close to the white equal-energy area are obtained with the thickness of DCJTB of 120 nm. Moreover, the CIE coordinate migrations of the flexible WOLED are less than (±0.02, ±0.02) in a wide range of driving voltages (from 6 V to 11 V) for the device, indicating the flexible WOLED has excellent color stability.关键词
柔性白色有机电致发光器件/色彩转换材料/色稳定性Key words
flexible white organic light-emitting devices/color conversion material/color stability分类
信息技术与安全科学引用本文复制引用
吴晓明,申利莹,华玉林,董木森,穆雪,白娟娟,毕文涛,杨小艳,印寿根..利用色彩转换法制备高色稳定性的柔性白色有机电致发光器件[J].物理学报,2012,61(17):553-558,6.基金项目
国家自然科学基金(批准号:60906022,60876046),天津市自然科学基金(批准号:10JCYBJC01100)和天津市高等学校科技发展基金计划重点项目(批准号:2011ZD02)资助的课题 ()