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利用色彩转换法制备高色稳定性的柔性白色有机电致发光器件

吴晓明 申利莹 华玉林 董木森 穆雪 白娟娟 毕文涛 杨小艳 印寿根

物理学报2012,Vol.61Issue(17):553-558,6.
物理学报2012,Vol.61Issue(17):553-558,6.

利用色彩转换法制备高色稳定性的柔性白色有机电致发光器件

Highly color-stability flexible white organic light-emitting devices fabricated by color conversion method

吴晓明 1申利莹 1华玉林 1董木森 1穆雪 1白娟娟 1毕文涛 1杨小艳 1印寿根1

作者信息

  • 1. 天津理工大学材料科学与工程学院,显示材料与光电器件教育部重点实验室,天津市光电显示材料与器件重点实验室,天津300384
  • 折叠

摘要

Abstract

We demonstrate flexible white organic light-emitting diode (WOLED) with high color stability, which combines vacuum deposited blue flexible organic light-emitting diode (FOLED) with red surface color conversion material (CCM). Firstly, we utilize the novel multiple quantum well (MQW), which consists of the alternate layers of 2, 3, 5, 6-Tetrafluoro-7, 7, 8, 8-tetracyano-quinodimethane (F4-TCNQ) and 4, 4′, 4″-tris-(N-3-methylphenyl-N-phenylamino) tripheny-lamine (m-MTDATA) as hole injection layer (HIL), through combining a new blue emitting material of N^6, N^6, N^12, N^12-tetrap-tolylchrysene-6, 12-diamine (NCA), to fabricate highly efficient blue FOLED. Then, the CCM of 4-(dicyanomethylene)-2-tert-butyl-6-(1, 1, 7, 7-tetramethyljul-oli-dyl-9-en-yl)-4H-pyran (DCJTB) is deposited on the outside of the ITO flexible substrate. Finally, the thickness of the color conversion film (CCF) is optimized to improve the color purity of flexible WOLED. The results demonstrate that at a driving voltage of 7 V, the CIE coordinates of (0.33, 0.27) which are very close to the white equal-energy area are obtained with the thickness of DCJTB of 120 nm. Moreover, the CIE coordinate migrations of the flexible WOLED are less than (±0.02, ±0.02) in a wide range of driving voltages (from 6 V to 11 V) for the device, indicating the flexible WOLED has excellent color stability.

关键词

柔性白色有机电致发光器件/色彩转换材料/色稳定性

Key words

flexible white organic light-emitting devices/color conversion material/color stability

分类

信息技术与安全科学

引用本文复制引用

吴晓明,申利莹,华玉林,董木森,穆雪,白娟娟,毕文涛,杨小艳,印寿根..利用色彩转换法制备高色稳定性的柔性白色有机电致发光器件[J].物理学报,2012,61(17):553-558,6.

基金项目

国家自然科学基金(批准号:60906022,60876046),天津市自然科学基金(批准号:10JCYBJC01100)和天津市高等学校科技发展基金计划重点项目(批准号:2011ZD02)资助的课题 ()

物理学报

OA北大核心CSCDCSTPCDSCI

1000-3290

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