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铌酸钾钠基无铅透明陶瓷制备及性能

王斌科 田晓霞 徐卓 屈绍波 李振荣

物理学报2012,Vol.61Issue(19):464-468,5.
物理学报2012,Vol.61Issue(19):464-468,5.

铌酸钾钠基无铅透明陶瓷制备及性能

Preparation and performances of KNN-based lead-free transparent ceramics

王斌科 1田晓霞 2徐卓 3屈绍波 2李振荣3

作者信息

  • 1. 西安交通大学电子材料研究所,西安710049 空军工程大学理学院,西安710051
  • 2. 空军工程大学理学院,西安710051
  • 3. 西安交通大学电子材料研究所,西安710049
  • 折叠

摘要

Abstract

Using conventional solid-phase sintering technique combined with a special atmosphere controlling technique, KNN-based lead- free transparent ceramics, xBa(Sc0.5Nb0.5)O3-(1 - x) (K0.5N0.5)NbO3 (xBSN-(1 - x) KNN), are prepared and investigated. Their microstructure, dielectric performance, ferroelectric performance and optical transparency are investigated. The results show that such ceramics are each with a pseudocubic-Perovskite structure, without any other impure phase. Their grain size is comparable to the light wavelength and the grains are highly condensed without evident crystal borders. For x = 0.05, the d33 reaches up to 110 pC/N maximally and the 2Px=25.4 μC/cm2. Moreover, such ceramics are each with an excellent transparency. Their optical transparency reaches about 54%, In the near-infrared wavelength 2500 nm, their optical transparency is near 83%. Such ceramics are a type of environment-friendly lead-free transparent ceramics which may be promising in replacing lead-based transparent ceramics.

关键词

铌酸钾钠/无铅透明陶瓷/透过率/晶界

Key words

KNN/lead-free transparent ceramics/transmission/crystal borders

分类

数理科学

引用本文复制引用

王斌科,田晓霞,徐卓,屈绍波,李振荣..铌酸钾钠基无铅透明陶瓷制备及性能[J].物理学报,2012,61(19):464-468,5.

基金项目

国家自然科学基金(批准号:10976022,50632030)和陕西省自然科学基金(批准号:2011JM6012)资助的课题. ()

物理学报

OA北大核心CSCDCSTPCDSCI

1000-3290

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