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流延法制备高热导率定向石墨/高分子复合片层材料

周绍鑫 祝渊 杜鸿达 李宝华 康飞宇

新型炭材料2012,Vol.27Issue(4):241-249,9.
新型炭材料2012,Vol.27Issue(4):241-249,9.DOI:10.1016/S1872-5805(12)60015-8

流延法制备高热导率定向石墨/高分子复合片层材料

Preparation of oriented graphite/polymer composite sheets with high thermal conductivities by tape casting

周绍鑫 1祝渊 2杜鸿达 1李宝华 2康飞宇2

作者信息

  • 1. 清华大学材料科学与工程系,新型陶瓷与精细工艺国家重点实验室,北京100084
  • 2. 清华大学深圳研究生院,深圳市热管理工程与材料重点实验室,广东深圳518055
  • 折叠

摘要

Abstract

Oriented graphite/polymer composite sheets were prepared using natural,crystalline flake graphites as raw materials,polyvinyl butyral as binders,polyethylene glycol and dibutyl phthalate as plasticizers by a tape-casting method at room temperature.The dependences of the binder contents and the blade heights on the orientation of the composite sheets were studied,and the effect of the orientation on the thermal conductivity was investigated.X-ray diffraction patterns and scanning electron microscope images showed that as-prepared samples showed different degrees of orientation.The thermal conductivity increased with the degree of orientation.The highest thermal conductivity of 490 W/( m· K) could be achieved by optimizing the binder contents and the blade heights.

关键词

天然鳞片石墨/流延法/定向排列/热导率

Key words

Natural crystalline flake graphite/Tape casting/Orientation/Thermal conductivity

分类

通用工业技术

引用本文复制引用

周绍鑫,祝渊,杜鸿达,李宝华,康飞宇..流延法制备高热导率定向石墨/高分子复合片层材料[J].新型炭材料,2012,27(4):241-249,9.

基金项目

国家自然科学基金(50802049,50972065 and 50902079),广东省创新团队(JP200806230010A). (50802049,50972065 and 50902079)

新型炭材料

OA北大核心CSCDCSTPCDSCI

1007-8827

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