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正长石去除镉离子的试验研究

刘瑞 王志华 于娜 徐强

中国非金属矿工业导刊Issue(4):20-23,25,5.
中国非金属矿工业导刊Issue(4):20-23,25,5.

正长石去除镉离子的试验研究

Experimental Studies of the Interaction of Aqueous Cadmium Ion With Orthoclase

刘瑞 1王志华 1于娜 1徐强1

作者信息

  • 1. 长春工程学院勘查与测绘工程学院,吉林长春130021
  • 折叠

摘要

Abstract

The interactions between cadmium-bearing solution and orthoclase have been studied in the conditions of different mixed periods and pH value, Cd-feldspar was synthesized. The concentrations of Cd2+ were reduced with the reaction time extending, the remove rate of Cd2+ was up to 96% after 120 hours. The Cd2+ removal effect is almost up to equilibrium, about 78.40%, in the weak acid condition about pH 6. The phase composition of the reaction results was determined by XRD, showing the silicate phase cadmium-bearing occurred. The analysis of XPS were used to ascertained that the Cd 3d5/2 binding energy is 406.12eV, suggesting that Cd entered the structure of orthoclase, ion exchange reaction happened and ion bond formed. Both reactions of adsorption and ion exchange were deduced for the removal of cadmium pollution. It is concluded that wide distributed and amount of feldspar has a function of treating the Cd2+ pollution in the water.

关键词

正长石/表面吸附/离子交换/镉污染

Key words

orthoclase/ surface adsorption/ ion exchange/ pollution of cadmium

分类

天文与地球科学

引用本文复制引用

刘瑞,王志华,于娜,徐强..正长石去除镉离子的试验研究[J].中国非金属矿工业导刊,2012,(4):20-23,25,5.

基金项目

国家自然基金项目(41172043) (41172043)

吉林省教育厅项目(2005156). (2005156)

中国非金属矿工业导刊

OACSTPCD

1007-9386

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