安徽大学学报（自然科学版）2012，Vol.36Issue(6)：104-108,5.
邻苯二胺磷酰氯缩环氧丙醇酯的合成和表征
Synthesis and characterization of phosphate-glycidol O-diaminobenzene phosphoramidate ( GDP )
摘要
Abstract
The new type phosphate, phosphate-glycidol O-diaminobenzene phosphoramidate(GDP) , was synthesized by the 1,2 - diaminobenzene, phosphorus oxychloride and glycidol. Using 1,2-diaminobenzene and phosphorus oxychloride as raw materials, O-phenylene diamine chloride (DP) was synthesized. Using DP and glycidol as raw materials, GDP was synthesized. Then the optimum synthetic process was obtained by orthogonal experimental design. The results showed that the optimum synthetic process was; in the first step, n(c6h8n2 ):n(POCl3)=1 :1- 3 , reaction time 9 h, reaction temperature 82℃ , the yield 88% ; in the second step, n(DP) :n(c3H6o2)- 1 :1,reaction time 24 h, reaction temperature 30 ℃, the yield 62. 3%. Chemical structure of the product was confirmed by IR, 1H NMR and melting point was measured.关键词
阻燃/膨胀阻燃剂/合成/正交实验/表征Key words
flame retardant/ intumescent flame retardant/ synthesis/ orthogonal test/ characterization分类
轻工纺织引用本文复制引用
郝杰,李启胜,杜隆超..邻苯二胺磷酰氯缩环氧丙醇酯的合成和表征[J].安徽大学学报（自然科学版）,2012,36(6):104-108,5.基金项目
安徽大学青年科学研究基金资助项目(2009QN010A) （2009QN010A）
