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废水厌氧生物处理过程的熵分析

刘前 戴友鹏 牟晓芳

安徽农业科学Issue(30):14625-14626,14635,3.
安徽农业科学Issue(30):14625-14626,14635,3.

废水厌氧生物处理过程的熵分析

Analysis of Entropy in the Processes of Anaerobic Wastewater Treatment

刘前 1戴友鹏 1牟晓芳1

作者信息

  • 1. 金华市环境科学研究院,浙江金华321017
  • 折叠

摘要

Abstract

[ Objective] The research aimed to provide the theoretical basis for the optimization of anaerobic wastewater treatment. [ Method] The entropy variations in the all anaerobic wastewater treatment processes were studied. [Result] In the stage of hydrolysis produced acid fermentation, ΔGθ <0, reactions conducted spontaneously, so ΔS>0. In the stage of hydrogen and acetate production, ΔGθ >0 in most of reactions, so Δ5 <0. But the use of hydrogen in the follow-up stage would promote reactions conducting to the right.In the stage of methanogene-sis, ΔGθ<0, reactions conducted spontaneously, so ΔS>0. [ Conclusion] Most of the reactions in anaerobic wastewater treatment processes are spontaneous. The phase of hydrogen and acid production is non-spontaneous stage. Extra energy and matter are needed in this stage in the view of thermodynamics.

关键词

废水/厌氧/

Key words

Wastewater/ Anaerobic/ Entropy

分类

农业科技

引用本文复制引用

刘前,戴友鹏,牟晓芳..废水厌氧生物处理过程的熵分析[J].安徽农业科学,2012,(30):14625-14626,14635,3.

安徽农业科学

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