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色氨酸复配缓蚀剂对碳钢在硫酸中的缓蚀性能

黄开宏 周坤 芮玉兰 曹毅

表面技术2012,Vol.41Issue(5):25-29,5.
表面技术2012,Vol.41Issue(5):25-29,5.

色氨酸复配缓蚀剂对碳钢在硫酸中的缓蚀性能

The Corrosion Inhibition of Tryptophan and Its Compound for Carbon Steel in H2SO4 Solution

黄开宏 1周坤 2芮玉兰 1曹毅1

作者信息

  • 1. 河北联合大学 化学工程学院,唐山 063009
  • 2. 河北化工医药职业技术学院 化工系,石家庄 050026
  • 折叠

摘要

Abstract

The tryptophan and its compound were tested as corrosion inhibitors for carbon steel Q235 in an aqueous solution of 0. 5 mol/L sulphuric acid by weight-loss and electrochemistry methods. The inhibitory mechanism was discussed by isothermal adsorption model and corrosion kinetics. The results show that single tryptophan has low corrosion inhibitor effect, while L-tryptophan and potassium iodide have certain synergistic effect, but synergistic effect with ascorbic acid is not significant. The three optimum amount of compound, the inhibition efficiency reaches 92. 43 % ; The L-tryptophan and ascorbic acid are mixed type inhibitors, whereas the potassium iodide and complex inhibitors are the anodic type; Tryptophan is absvrbed on the surface of carbon steel by chemisorption adsorbed, in line with the Langmuir adsorption isotherm.

关键词

色氨酸/协同效应/缓蚀剂/吸附等温模型

Key words

tryptophan/ synergistic effect/ corrosion inhibitor/ isothermal adsorption model

分类

矿业与冶金

引用本文复制引用

黄开宏,周坤,芮玉兰,曹毅..色氨酸复配缓蚀剂对碳钢在硫酸中的缓蚀性能[J].表面技术,2012,41(5):25-29,5.

基金项目

河北省教育厅项目(2009330) (2009330)

表面技术

OA北大核心CSCDCSTPCD

1001-3660

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