| 注册

氟化聚苯胺的合成及性能

于庆杰 许建明

重庆理工大学学报:自然科学2012,Vol.26Issue(11):45-48,4.
重庆理工大学学报:自然科学2012,Vol.26Issue(11):45-48,4.

氟化聚苯胺的合成及性能

Syntheses and Characterization of Polyfluoroaniline

于庆杰 1许建明1

作者信息

  • 1. 华侨大学化工学院,厦门361021
  • 折叠

摘要

Abstract

Polyaniline and polyfluoroaniline have been synthesized by semi-continuous emulsion polymerization using twelve alkyl ammonium sodium(SDS),ammonium persulfate(APS),aniline(ANI) and 3-fluoroaniline(FANI),respectively.The morphology and properties of polyaniline and polyfluoroaniline were investigated by TGA,FTIR,SEM and contact angles measurement.Experimental results demonstrated that,the particle size of nanospherical PFANI is about 100 nm and present free self-aggregate.Moreover,the stability of PFANI emulsion was higher than that of PANI emulsion significantly.It was also found that the PFANI film prepared was very hydrophobic and exhibited excellent water repellency,due to the present of C-F group.

关键词

氟化聚苯胺/乳液聚合/疏水性能

Key words

polyfluoroaniline/emulsion polymerization/water-repellent

分类

化学化工

引用本文复制引用

于庆杰,许建明..氟化聚苯胺的合成及性能[J].重庆理工大学学报:自然科学,2012,26(11):45-48,4.

基金项目

福建省自然科学基金资助项目 ()

重庆理工大学学报:自然科学

OACSTPCD

1674-8425

访问量0
|
下载量0
段落导航相关论文