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用作超级电容器的聚苯胺基活性炭材料

刘恩辉 田莹莹 胡添添 毛朝辉 杨晶晶

电源技术2012,Vol.36Issue(11):1643-1646,4.
电源技术2012,Vol.36Issue(11):1643-1646,4.

用作超级电容器的聚苯胺基活性炭材料

Polyaniline-based activated carbon as supercapacitor

刘恩辉 1田莹莹 1胡添添 1毛朝辉 1杨晶晶1

作者信息

  • 1. 湘潭大学化学学院,湖南湘潭411105
  • 折叠

摘要

Abstract

A novel activated carbon was prepared from polyaniline which was prepared by the oxypolymerizaton of aniline and activated by ZnCI, at the temperature of 800 t .The prepared materials were characterized by X-ray photoelectron spectroscopy, Boehm titration and BET. The electrochemical properties were studied by using cyclic voltammograms, galvanostatic charge/discharge in 6.0 mol/l KOH solution. The activation carbon presents a high specific gravimetric specific capacitance of 174 F/g at a scan rate of 2 mV/s. The specific capacitance decreases of 3.5% at a current density of 500 mA/g after 2 000 cycles. The results show that its high capacity and stability is due to the increased surface area after ZnCl2 activation, and oxygen and nitrogen groups contributed pseudocapacitance.

关键词

聚苯胺/活性炭/氯化锌活化/超级电容器

Key words

polyaniline/ activated carbon/ ZnCI/ supercapacitor

分类

信息技术与安全科学

引用本文复制引用

刘恩辉,田莹莹,胡添添,毛朝辉,杨晶晶..用作超级电容器的聚苯胺基活性炭材料[J].电源技术,2012,36(11):1643-1646,4.

基金项目

感谢国家自然科学基金(51172190)和湖南省自然科学基金(11JJ2030)的经费支持. (51172190)

电源技术

OA北大核心CSCDCSTPCD

1002-087X

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