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C-S-H凝胶对Pb(Ⅱ)的吸附固化作用

王昕 刘晶 汪澜 考宏涛

硅酸盐通报2012,Vol.31Issue(5):1039-1043,5.
硅酸盐通报2012,Vol.31Issue(5):1039-1043,5.

C-S-H凝胶对Pb(Ⅱ)的吸附固化作用

Adsorption and Solidification of Pb(Ⅱ) by C-S-H Gel

王昕 1刘晶 2汪澜 1考宏涛2

作者信息

  • 1. 中国建筑材料科学研究总院绿色建筑材料国家重点实验室,北京100024
  • 2. 南京工业大学材料科学与工程学院,南京210009
  • 折叠

摘要

Abstract

In order to investigate the adsorption and solidification of Pb(II) , pure C-S-H gel and Pb-doped C-S-H gel were synthesized using analytical reagent grade Ca(NO3)2·4H2O、Na2SiO3·9H2O and Pb ( NO3) 2 as raw materials by the solution reaction. The results showed the C-S-H gel had good adsorption ability while soluble lead salts increased from 2% to 6% . The X-ray diffraction patterns of Pb-doped C-S-H gel changed obviously,both in peak shift and the emergence of Ca(OH)2 diffraction peaks. Infrared tests showed that Si linkage models had been changed in the way that Q2 stretching vibration shifted to lower wavenumber and Q stretching vibration peak absorption intensity increased, specially for silicon-oxide tetrahedron structure existing in Pb-doped C-S-H gel.

关键词

C-S-H凝胶/Pb(Ⅱ)/吸附固化

Key words

C-S-H gel/Pb(II) /adsorption and solidification

分类

建筑与水利

引用本文复制引用

王昕,刘晶,汪澜,考宏涛..C-S-H凝胶对Pb(Ⅱ)的吸附固化作用[J].硅酸盐通报,2012,31(5):1039-1043,5.

基金项目

国家重点基础研究发展计划(973计划)项目资助(2010CB735803) (973计划)

硅酸盐通报

OA北大核心CSCDCSTPCD

1001-1625

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