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SiO2/CaO质量比对白云鄂博尾矿微晶玻璃的影响研究

杜永胜 李保卫 张雪峰 贾晓林 赵鸣 陈华 邓磊波

硅酸盐通报2012,Vol.31Issue(5):1092-1095,4.
硅酸盐通报2012,Vol.31Issue(5):1092-1095,4.

SiO2/CaO质量比对白云鄂博尾矿微晶玻璃的影响研究

Effect of SiO2/CaO Ratio on the Structure and Properties of Baiyunebo Tailing/fly Ash Glass-ceramics

杜永胜 1李保卫 2张雪峰 3贾晓林 3赵鸣 4陈华 3邓磊波1

作者信息

  • 1. 内蒙古工业大学,材料科学与工程学院,呼和浩特010051
  • 2. 内蒙古科技大学数理与生物工程学院,包头014010
  • 3. 内蒙古科技大学内蒙古自治区白云鄂博多金属资源综合利用重点实验室,省部共建国家重点实验室培育基地,包头014010
  • 4. 郑州大学材料学院,郑州450052
  • 折叠

摘要

Abstract

Glass-ceramics of CaO-MgO-Al2O3-SiO2 quaternary system were successfully produced by the method of melting, using Baiyunebo tailing and fly ash as main sources of raw materials. The effect of SiO2/CaO ratio on the structure and properties of the glass-ceramics have been investigated by X-ray diffraction ( XRD ) , differential thermal analysis ( DTA ) and scanning electron microscope (SEM ). The results showed that with the increase of SiO2/CaO ratio the crystallization temperature of as-cast glasses were shifted to higher temperatures and the intensity of exothermic peaks were gradually reduced. The main crystalline phases of glass-ceramic were changed from augite to magnetite. Moreover, it can be seen that the crystallite size was decreased and the degree of crystallization was gradually weaken with the mass ratio of SiO2/CaO increased. This contributed mainly to the decrease in the properties of the glass-ceramics.

关键词

微晶玻璃/SiO2/CaO比/白云鄂博尾矿/辉石相

Key words

glass-ceramics/ SiO2/CaO ratio/ Baiyunebo tailing/ augite

分类

化学化工

引用本文复制引用

杜永胜,李保卫,张雪峰,贾晓林,赵鸣,陈华,邓磊波..SiO2/CaO质量比对白云鄂博尾矿微晶玻璃的影响研究[J].硅酸盐通报,2012,31(5):1092-1095,4.

基金项目

国家重点基础研究发展计划(973计划,2012CB722802) (973计划,2012CB722802)

内蒙古科技大学创新基金(2011NCL034) (2011NCL034)

内蒙古创新引导基金(20111623) (20111623)

硅酸盐通报

OA北大核心CSCDCSTPCD

1001-1625

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