化工进展2012，Vol.31Issue(12)：2666-2671,2685,7.
La-Ni（Co）-Mo-B非晶态催化剂催化苯甲醛、苯乙酮加氢脱氧反应
Hydrodeoxygenation of benzaldehyde and acetophenone on La-Ni(Co)-Mo-O-B amorphous catalysts
摘要
Abstract
In this paper,La-Ni-Mo-B and La-Co-Mo-B amorphous catalysts were prepared by the chemical reduction method and their hydrodeoxygenation(HDO)activities were determined by using benzaldehyde and acetophenone as model compounds.The results showed that La-Ni-Mo-B and La-Co-Mo-B had amorphous structure and both conversion and deoxygenation rate reached to 100.0% on these two catalysts.The deoxygenation products such as toluene or ethylbenzene could be further hydrogenated to the corresponding cycloalkanes on La-Ni-Mo-B amorphous catalyst because of its high hydrogenation activity due to electron transfer between Ni0 and B0,leading to low aromatic content in the product,which met the demand of clean fuel.关键词
非晶态催化剂/加氢脱氧/苯甲醛/苯乙酮/生物油Key words
amorphous catalyst/hydrodeoxygenation/benzaldehyde/acetophenone/bio-oil分类
化学化工引用本文复制引用
杨彦松,彭会左,杨运泉,刘文英,张小哲,王威燕..La-Ni（Co）-Mo-B非晶态催化剂催化苯甲醛、苯乙酮加氢脱氧反应[J].化工进展,2012,31(12):2666-2671,2685,7.基金项目
湘潭大学资助 （）
湖南省教育厅开放基金（10K062）项目 （）
