化工进展2012，Vol.31Issue(12)：2694-2701,2719,9.
手性修饰催化剂在多相不对称氢化中的研究进展
Progress of heterogeneous asymmetric hydrogenation on chirally modified catalysts
摘要
Abstract
Chirally modified metal catalysts are one of most developed and promising heterogeneous enantioselective catalysts.The recent progress of the enantioselective hydrogenation of β-ketoesters on tartaric acid modified nickel catalysts,the enantioselective hydrogenation of α-ketoesters using cinchona alkaloid modified platinum,and the enantioselective hydrogenation of carbon-carbon and carbon-nitrogen double bonds using cinchona alkaloid modified palladium catalysts are summarized.The influential factors of the catalyst systems are briefly introduced,and the enantioselection mechanism in tartaric acid modified nickel catalysts and cinchona alkaloids modified platinum catalysts are also discussed.In addition,further research work in heterogeneous asymmetric hydrogenation should be focused on development of high efficiency catalysts and investigation of reaction mechanism.关键词
多相催化/不对称氢化/手性催化剂/酒石酸/金鸡纳生物碱Key words
heterogeneous catalysis/enantioselective hydrogenation/chiral catalyst/tartaric acid/cinchona alkaloids分类
化学化工引用本文复制引用
何年志,张学勤,肖美添..手性修饰催化剂在多相不对称氢化中的研究进展[J].化工进展,2012,31(12):2694-2701,2719,9.基金项目
福建省自然科学基金 （）
华侨大学科研基金（10DS314）项目 （）
