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超声波/零价铁降解水中双酚A

赵生培 王东田 周颖 李学艳 黄勇

环境工程学报2012,Vol.6Issue(12):4417-4422,6.
环境工程学报2012,Vol.6Issue(12):4417-4422,6.

超声波/零价铁降解水中双酚A

Degradation of bisphenol A from water by ultrasound/zero-valent iron

赵生培 1王东田 2周颖 1李学艳 1黄勇1

作者信息

  • 1. 苏州科技学院江苏省环境科学与工程重点实验室,苏州215011
  • 2. 苏州科技学院江苏省环境科学与工程重点实验室,苏州215011 苏州科技学院化学与生物工程学院,苏州215009
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摘要

Abstract

The efficiency and affecting factors of bisphenol A (BPA) degradation in water were studied by uhrasound/zero-valent iron (US/Fe^0). The experimental results indicated that US/Fe^0 was more effective to de- grade BPA than US or Fe^0 alone in water. Fe^0 existed synergistic effects on the degradation of BPA. The degra- dation process was well described by the first-order kinetics. The Fe^0 had dual function for promoting and inhibi- ting degradation. The greater of ultrasonic power, the better of the degradation rate of BPA. When the initial concentration of BPA is lower, the degradation rate of BPA becomes greater. The condition of lower pH value is conducive to the degradation of BPA. The presence of hydroxyl radical capture (n-butanol) restrains the degra- dation efficiency of bisphenol A. Combining US with Fe^0 to treat BPA for 2 h, the TOC removal is little,which shows that the mineralization efficiency of BPA is incomplete.

关键词

超声波/零价铁/双酚A/协同/降解

Key words

ultrasound/zero-valent iron/bisphenol A/synergism/degradation

分类

资源环境

引用本文复制引用

赵生培,王东田,周颖,李学艳,黄勇..超声波/零价铁降解水中双酚A[J].环境工程学报,2012,6(12):4417-4422,6.

基金项目

国家科技重大专项子项目 ()

环境工程学报

OA北大核心CSCDCSTPCD

1673-9108

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