含能材料2012，Vol.20Issue(5)：596-600,5.DOI:10.3969/j.issn.1006-9941.2012.05.017
对二甲氨基苯基五唑和对羟基苯基五唑的低温合成与NMR表征
Synthesis and NMR Characterization of p-Dimethylaminophenylpentazole and p-Hydroxyphenylpentazole at Low Temperature
徐敏 1毕福强 1张皋 1王民昌 1葛忠学 1陈智群 1许诚1
作者信息
- 1. 西安近代化学研究所,陕西西安710065
- 折叠
摘要
Abstract
p-Dimethylaminophenylpentazole( p-DMAPP) and p-hydroxyphenylpentazole( p-HPP) were synthesized at -40 ℃ , using N1 ,N1 -dimethylbenzene-1 ,4-diamine and 4-aminophenol as starting meaterials, respectively. Their stuctures were characterized by 'H NMR, 13C NMR , 'H-13C HMBC, 15N NMR and ' H-15 N HMBC at low temperature. The results show that the ' H NMR and 13C NMR data of p-DMAPP and p-HPP are in accordant with the literature values. Nitrogen signals of pentazole are assigned as N-1 (δN -80.0) , N-2/5(δN -27.3) , N-3/4(δN 5.1 ) for p-DMAPP and N-1 (δN -84.1 ) , N-2/5(δN -28.1 ) , N-3/4 (δN4.2) for p-HPP, respectively.关键词
有机化学/对二甲胺基苯基五唑/对羟基苯基五唑/合成/核磁共振Key words
organic chemistry/ p-dimethylaminophenylpentazole/ p-hydroxyphenylpentazole/ synthesis/ NMR分类
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徐敏,毕福强,张皋,王民昌,葛忠学,陈智群,许诚..对二甲氨基苯基五唑和对羟基苯基五唑的低温合成与NMR表征[J].含能材料,2012,20(5):596-600,5.
