火炸药学报2012，Vol.35Issue(5)：41-44,4.
FT-IR法研究键合剂与N-100的反应动力学
Study on the Reaction Kinetics of Bonding Agents and N-100 by FT-IR
摘要
Abstract
The reaction kinetics of bonding agents and N-100 was studied by FT-IR. The reaction rate constant and activation energy were obtained. The mechanical properties of the bonding agent were validated. The results show that, two reactions of W01/N-100 and BAG01/N-100 are determined as second order reaction. The activation energies are 33. 35 kJ/mol for W01/N-100 and 32. 26 kJ/mol for BAG01/N-100. The reaction rate rises with increasing of reaction temperature. The mechanical performance of propellant was improved by N-100, and the effect of bonding agent W01 was better than bonding agent BAG01. Bonding agent of W01 was more suitable for glycidylazi-dopolymer(GAP).关键词
物理化学/反应动力学/键合剂/FT-IR光谱/N-100Key words
physical chemistry/ reaction kinetics/ bonding agents/ FT-IR spectrum/ N-100分类
军事科技引用本文复制引用
武卓,李洪旭,庞爱民,陶博文,周桓,王拯,李尚文..FT-IR法研究键合剂与N-100的反应动力学[J].火炸药学报,2012,35(5):41-44,4.基金项目
总装备部预先研究项目(51328040101) （51328040101）
