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氮掺杂碳气凝胶电极材料的制备及性能

刘西川 袁磊 冯灏 付志兵 王朝阳 孙卫国 唐永建

强激光与粒子束2012,Vol.24Issue(12):2848-2852,5.
强激光与粒子束2012,Vol.24Issue(12):2848-2852,5.DOI:10.3788/HPLPB20122412.2848

氮掺杂碳气凝胶电极材料的制备及性能

Preparation and performance of nitrogen-doped carbon aerogels as electrode materials

刘西川 1袁磊 2冯灏 1付志兵 2王朝阳 1孙卫国 1唐永建2

作者信息

  • 1. 中国工程物理研究院激光聚变研究中心,四川绵阳621900
  • 2. 西华大学材料科学与工程学院,成都610039
  • 折叠

摘要

Abstract

Nitrogen-doped carbon aerogels (NCAs) were synthesized from melamine, resorcinol and formaldehyde by sol-gel, supercritical drying and high-temperature carbonization process. The structure properties and function of the NCAs were characterized by means of XPS, SEM and nitrogen adsorption, showing that the nitrogen was successfully doped into carbon aerogels. Meanwhile, the N-doping content and the microstructures of the NCAs distinctly depend on the amount of melamine. Besides, the electrochemical performances of the NCAs were tested by galvanostatic charge-discharge and cyclic voltammetry in 6 mol/L KOH solution, and the results indicate that their electrochemical performances are greatly improved after N-doping with the highest specific capacitance reaching 176 F·g-1.

关键词

氮掺杂/碳气凝胶/三聚氰胺/超级电容器/比电容

Key words

nitrogen-doped/ carbon aerogels/ melamine/ super capacitor/ specific capacitance

分类

化学化工

引用本文复制引用

刘西川,袁磊,冯灏,付志兵,王朝阳,孙卫国,唐永建..氮掺杂碳气凝胶电极材料的制备及性能[J].强激光与粒子束,2012,24(12):2848-2852,5.

基金项目

中国工程物理研究院科学技术发展基金项目(2009A0302020,2010B0401056) (2009A0302020,2010B0401056)

强激光与粒子束

OA北大核心CSCDCSTPCD

1001-4322

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