人工晶体学报2012，Vol.41Issue(5)：1286-1290,1297,6.
Ag@AgCl/Ag3PO4的可见光光催化性能及机理研究
Visible Light Photocatalytic Performance and Mechanism of Ag@AgCl/Ag3PO4
摘要
Abstract
Photocatalytic material of Ag @ AgCl/Ag3PO4 responded to visible light was prepared by precipitation replacement method and characterized by using XRD, UV-vis and XPS analysis methods in detail. The degradation of methyl orange in water was chosen as a probe reaction to study the photocatalytic activity of Ag @ AgCl/Ag3PO4 under visible light irradiation. The Ag@ AgCl/Ag3PO4 catalyst had complete crystal form, the narrow band-gap, and excellent absorption capacity for visible light clearly showed from XRD and UV-Vis absorption spectra results. SEM analysis results showed that the catalyst particles were 0. 5 μm or so. XPS spectra indicated that the content of Ag+ and Ag existed on catalyst surface was significantly enhanced. Experimental results showed that the main reasons for high photocatalytic activity of Ag@ AgCl/Ag3PO4 may be reduce of band-gap, synergistic effect of the surface plasma resonance effect between Ag0 and AgCl and strong oxidizing of Cl .关键词
Ag@AgCl/Ag3PO4/光催化/可见光/甲基橙Key words
Ag@ AgCl/Ag3 PO4 / photocatalysis/ visible light/ methyl orange分类
化学化工引用本文复制引用
王韵芳,王雅文,丁光月,樊彩梅..Ag@AgCl/Ag3PO4的可见光光催化性能及机理研究[J].人工晶体学报,2012,41(5):1286-1290,1297,6.基金项目
国家自然科学基金(21176168,21206105) （21176168,21206105）
山西省科技攻关项目(20090311082) （20090311082）
