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镓掺杂氧化锌透明导电薄膜的制备及其性能研究

钟志有 顾锦华 孙奉娄 杨春勇 侯金

人工晶体学报2012,Vol.41Issue(5):1337-1344,8.
人工晶体学报2012,Vol.41Issue(5):1337-1344,8.

镓掺杂氧化锌透明导电薄膜的制备及其性能研究

Preparation and Properties of Gallium-doped Zinc Oxide Transparent Conductive Thin Films

钟志有 1顾锦华 2孙奉娄 3杨春勇 1侯金2

作者信息

  • 1. 中南民族大学电子信息工程学院,武汉430074
  • 2. 中南民族大学等离子体研究所,武汉430074
  • 3. 中南民族大学计算与实验中心,武汉430074
  • 折叠

摘要

Abstract

Highly conduct gallium-doped zinc oxide (Ga∶ ZnO)transparent thin films were prepared on the glass substrates by radio-frequency (RF) magnetron sputtering.The deposited films were characterized by X-ray diffraction (XRD),X-ray photoelectron spectroscopy (XPS),four-point probe and spectrophotometer,respectively.The influence of the substrate temperature on the structural,compositional,optical and electrical properties of the films was investigated.The results show that high quality Ga∶ ZnO films oriented with their crystallographic c-axis perpendicular to the substrates are obtained.The crystal structures and optoelectrical properties of the films are highly dependent on the substrate temperature.The Ga∶ ZnO films fabricated at the substrate temperature of 673 K exhibit the best optoelectronic properties,which have the maximum crystallite size (72.6 nm),the lowest resistivity (1.3× 10-3 Ω·cm),the higher average visible transmittance (88.9%) and the highest figure of merit (1.4 ×10-2 S).Furthermore,the energy gap of the films was calculated by extrapolation method.A blue shift of the optical energy gap is observed with an increase in the substrate temperature.

关键词

氧化锌薄膜/磁控溅射/光电性能

Key words

zinc oxide thin films/ magnetron sputtering/ optoelectrical properties

分类

数理科学

引用本文复制引用

钟志有,顾锦华,孙奉娄,杨春勇,侯金..镓掺杂氧化锌透明导电薄膜的制备及其性能研究[J].人工晶体学报,2012,41(5):1337-1344,8.

基金项目

Project supported by the Natural Science Foundation of Hubei (2011CDB418),the National Natural Science Foundation of China (61002013,11147014),and the Academic Team Foundation (XTZ09003) of SCUN (2011CDB418)

人工晶体学报

OA北大核心CSCDCSTPCD

1000-985X

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