燃料化学学报2012，Vol.40Issue(11)：1281-1288,8.
神华煤直接液化残渣萃取残渣焦气化动力学研究
Gasification kinetics of extraction residue char from Shenhua direct liquefaction residue
刘朋飞 1张永奇 2房倚天1
作者信息
- 1. 中国科学院山西煤炭化学研究所,山西太原030001
- 2. 中国科学院研究生院,北京100049
- 折叠
摘要
Abstract
Thermo-gravimetric analysis was employed to study gasification kinetics of three coal direct liquefaction extract residue chars under steam and CO2 atmosphere. Gasification kinetics of liquefaction residue char was compared at the same conditions. It is shown that temperature plays a significant role on residue char gasification. The decreasing degree of order for carbon and increasing pore structure in residue chars due to supercritical solvent extraction improve gasification reactivity of residue chars. Due to the lack of pore structure, the experimental results of residue chars during steam gasification and CO2 gasification can be well described by the chemical reaction control shrinking core model.关键词
液化残渣/萃取残渣/水蒸气气化/CO2气化/动力学Key words
liquefaction residue/ extract residue/ steam gasification/ CO2 gasification/ dynamic kinetics分类
化学化工引用本文复制引用
刘朋飞,张永奇,房倚天..神华煤直接液化残渣萃取残渣焦气化动力学研究[J].燃料化学学报,2012,40(11):1281-1288,8.
