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铈铝复合载体对钼基催化剂耐硫甲烷化催化性能的研究

王保伟 尚玉光 丁国忠 王海洋 王二东 李振花 马新宾 秦绍东 孙琦

燃料化学学报2012,Vol.40Issue(11):1390-1396,7.
燃料化学学报2012,Vol.40Issue(11):1390-1396,7.

铈铝复合载体对钼基催化剂耐硫甲烷化催化性能的研究

Ceria-alumina composite support on the sulfur-resistant methanation activity of Mo-based catalyst

王保伟 1尚玉光 1丁国忠 1王海洋 1王二东 1李振花 1马新宾 1秦绍东 2孙琦2

作者信息

  • 1. 天津大学化工学院绿色合成与转化教育部重点实验室,天津300072
  • 2. 北京低碳清洁能源研究所,北京102209
  • 折叠

摘要

Abstract

Ceria-alumina composite supports were prepared by co-precipitation, impregnation and deposition-precipitation method, respectively. Co-Mo catalysts supported on the composite supports were evaluated for sulfur-resistant methanation and the appropriate content of CeO2 in the composite support was further studied. All the samples were characterized by nitrogen adsorption, X-ray diffraction (XRD) and hydrogen temperature-programmed reduction (H2-TPR). It was found that addition of CeO2 to A12O3 significantly increased the activity of methanation and 25% CeO2-Al2O3 prepared by deposition-precipitation method had the best sulfur-resistant methanation activity.

关键词

氧化铈/氧化铝/复合载体/钴钼催化剂/耐硫甲烷化

Key words

ceria/ alumina/ composite support/ Co-Mo catalyst/ sulfur-resistant methanation

分类

化学化工

引用本文复制引用

王保伟,尚玉光,丁国忠,王海洋,王二东,李振花,马新宾,秦绍东,孙琦..铈铝复合载体对钼基催化剂耐硫甲烷化催化性能的研究[J].燃料化学学报,2012,40(11):1390-1396,7.

燃料化学学报

OA北大核心CSCDCSTPCD

2097-213X

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