石油化工2012，Vol.41Issue(9)：1028-1033,6.
液体脱硫醇催化剂的性能评价
Performance Evaluation of Liquid Catalysts for Removal of Mercaptan
摘要
Abstract
Multi-sulfonated cobalt phthalocyanine was synthesized by the reaction of cobalt phthalocynine with chlorosulfonic acid, and then a liquid catalyst(Cat.A) with 23.8%(w) of the multi-sulfonated cobalt phthalocyanine as the active component for the removal of mercaptans from gasoline was prepared by dissolving the active component in sodium hydroxide solution with a stabilizer and an antifreezer. Cat.A was characterized by sulfur content analysis, dynamic light scattering analysis and potentiometric titration to investigate its structure, size distribution and catalytic activity, and compared with imported and domestic liquid desulfurization catalysts. The experimental results show that the average sulfonic group number in the every multi-sulfonated cobalt phthalocyanine molecule in Cat.A is 3.4. The active component in the alkali solution has good dispersity, solubility and stability. The removal rate of the mercaptans in gasoline could reach 90% using Cat.A under the conditions of the catalyst mass concentration 100 μg/g, the catalyst dosage 3 mL, gasoline with 255 μg/g of mercaptan sulfur mass concentration 30 mL, reaction temperature 30 ℃. and reaction time 30 min.关键词
液体催化剂/磺化酞菁钴/汽油脱硫醇Key words
liquid catalyst/ sulfonated cobalt phthalocyanine/ removal of mercaptan from gasoline分类
化学化工引用本文复制引用
江胜娟,孙小明,张桅,周玉路,项玉芝,夏道宏..液体脱硫醇催化剂的性能评价[J].石油化工,2012,41(9):1028-1033,6.基金项目
山东省自然基金资助项目(2009ZRA05107). （2009ZRA05107）
