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超支化聚酯与聚丙烯共混物的结晶及力学性能

樊庆春 段菲红 郭怀兵 吴田

武汉工程大学学报2012,Vol.34Issue(10):54-57,4.
武汉工程大学学报2012,Vol.34Issue(10):54-57,4.DOI:10.3969/j.issn.1674-2869.2012.10.013

超支化聚酯与聚丙烯共混物的结晶及力学性能

Mechanical properties and crystallization of polypropylene and hyperbranched polyester blends

樊庆春 1段菲红 1郭怀兵 1吴田1

作者信息

  • 1. 武汉工程大学化工与制药学院,绿色化工过程教育部重点实验室,湖北省新型反应器与绿色化学工艺重点实验室,湖北武汉430074
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摘要

Abstract

Blends composed of AB2 type hyperbranched polyester (HBP) and polypropylene (PP) were prepared by melt blending method. Effects of amounts of HBP on crystallinity and crystallization rate of blends were investigated by differential scanning calorimetry (DSC). Fracture surface of the blends was observed by scanning electron microscopy (SEM). The influence of the content of HBP on the mechanical properties of the blends was studied. The results show that HBP acts as a nucleating agent for PP during crystallization; The crystallization rate and the crystallinity of PP are increased with hyperbranched polyester added. When the content of hyperbranched polyester is 10% ? The crystallinity is 32. 15% and increases by 32. 63%. The tensile strength is improved with low amounts of HBP. When the content of hyperbranched polyester is 2% , the tensile strength reaches a maximum 36. 2 Mpa and increases by 7. 10%. The maximum impact strength of PP is 5. 80 kJ/m2 and increases by about 12. 60% when the content of hyperbranched polyester is 10%.

关键词

结晶度/增韧/冲击强度

Key words

crystallinity/ toughening/ impact strength

分类

化学化工

引用本文复制引用

樊庆春,段菲红,郭怀兵,吴田..超支化聚酯与聚丙烯共混物的结晶及力学性能[J].武汉工程大学学报,2012,34(10):54-57,4.

基金项目

武汉工程大学青年基金(Q200902) (Q200902)

武汉工程大学学报

1674-2869

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