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含酯基联接基的双子表面活性剂的合成及性能

马小单 李华静 李远刚 周安宁

西安科技大学学报2012,Vol.32Issue(5):627-631,5.
西安科技大学学报2012,Vol.32Issue(5):627-631,5.

含酯基联接基的双子表面活性剂的合成及性能

Synthesis and properties of Gemini surfactants with ester group in the spacer

马小单 1李华静 2李远刚 1周安宁2

作者信息

  • 1. 广州蓝月亮实业有限公司开发部,广东广州510760
  • 2. 西安科技大学化学与化工学院,陕西西安710054
  • 折叠

摘要

Abstract

Two quaternary ammonium type Gemini surfactants with ester group in the spacer, N, N'-didodecyl-N, N, N', N'-teramethyl-di-(2-aminoethanol)-adipate-dibromide ammonium ( DTAD) and N, N'-didodecyl-N, N, N', N'-teramethyl-di-( 2-aminoethanol) terephthalate-dibromide ammonium ( DTTD) were synthesized. The molecular structures were characterized by NMR and element analysis. The critical micelle concentration (cmc) , ionization degree of micelle ( a ) , foaming ability and foam stability were measured. The results show that DTAD has higher cmc, a than DTTD. But its foaming ability and foam stability is lower than that of DTTD. These results imply that the structure of the spacer has an important influence on the properties of Gemini surfactants.

关键词

双子表面活性剂/酯基联接基/表面活性

Key words

Gemini surfactants/ ester group in the spacer/ surface activity

分类

化学化工

引用本文复制引用

马小单,李华静,李远刚,周安宁..含酯基联接基的双子表面活性剂的合成及性能[J].西安科技大学学报,2012,32(5):627-631,5.

基金项目

国家自然科学基金项目(20943001) (20943001)

陕西省科学技术研究发展计划项目(2011K08-21) (2011K08-21)

西安科技大学学报

OACSTPCD

1672-9315

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