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巯基苯基卟啉自组装膜的制备及其光电性质

杨建东 崔文辉

西北师范大学学报(自然科学版)2012,Vol.48Issue(6):59-63,5.
西北师范大学学报(自然科学版)2012,Vol.48Issue(6):59-63,5.

巯基苯基卟啉自组装膜的制备及其光电性质

Preparation and photoelectric properties of porphyrin self-assembled monolayers

杨建东 1崔文辉1

作者信息

  • 1. 陇南师范高等专科学校生物化学系,甘肃成县742500
  • 折叠

摘要

Abstract

Tetra-[p-(3-mercaptopropyloxy)-phenyl3 porphyrin(TPP(SH)4) is synthesized and characterizated by UV, FI-IR and ' HNMR. Porphyrin self-assembled monolayers(SAMs) is prepared and demonstrated by UV, electrochemical methods spectrum and XPS spectrum. On this basis, self-assembled nanojunctions of TPP(SH)4 are fabricated by using gold nanogap electrodes. The nanojunctions exhibite current-voltage characteristics. With the light on/off, the nanojunctions exhibite excellect switch effect. TPP(SH)4 SAMs may be as photo switcher in nanoscale.

关键词

多巯基苯基卟啉/自组装膜/光电性质

Key words

multi-thiol substituted porphyrin compounds/ self-assembled monolayer/ photoelectric properties

分类

化学化工

引用本文复制引用

杨建东,崔文辉..巯基苯基卟啉自组装膜的制备及其光电性质[J].西北师范大学学报(自然科学版),2012,48(6):59-63,5.

基金项目

甘肃省自然科学基金资助项目(1107RJZK243) (1107RJZK243)

陇南师专校级重点科研启动金资助项目(2012LSZK01003) (2012LSZK01003)

西北师范大学学报(自然科学版)

OA北大核心CSTPCD

1001-988X

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