应用化学2012，Vol.29Issue(9)：1017-1022,6.DOI:10.3724/SP.J.1095.2012.00444
镁铝水滑石负载MnO-4催化氧化乙苯合成苯乙酮
Catalytic Oxidation of Ethylbenzene to Acetophenone Using Mg-Al Hydrotalcite-Supported MnO-4 Catalyst
汪一帆 1周维友 1方筱 1陈群1
作者信息
- 1. 常州大学石油化工中心省级重点实验室 常州213164
- 折叠
摘要
Abstract
The liquid-phase selective oxidation of ethylbenzene to acetophenone by oxygen using MnO4-exchanged Mg-Al-hydrotalcite as catalyst has been investigated in the absence of solvent. The effects of catalyst dosage, reaction temperature and reaction time on the yield of acetophenone and the conversion of ethylbenzene have been studied. Under the following optimized conditions: catalyst 3 g, ethylbenzene 45 mL, reaction temperature 120℃ , the oxygen flow velocity 100 mL/min, the yield and selectivity of acetophenone can be up to 57.0% and 96.3%, respectively. The catalyst retained high catalytic activity after three recylclings.关键词
水滑石/乙苯/绿色氧化/苯乙酮Key words
hydrotalcite, ethylbenzene, green oxidation, acetophenone分类
化学化工引用本文复制引用
汪一帆,周维友,方筱,陈群..镁铝水滑石负载MnO-4催化氧化乙苯合成苯乙酮[J].应用化学,2012,29(9):1017-1022,6.
