应用化学2012，Vol.29Issue(10)：1117-1122,6.DOI:10.3724/SP.J.1095.2012.00513
固相法合成苯胺与邻甲氧基苯胺共聚物及其性能
Solid-state Synthesis and Properties of Copolymers of Aniline and o-Methoxyaniline
摘要
Abstract
Copolymers of aniline and o-methoxyaniline were synthesized by solid-state polymerization method using methanesulphonic acid as the doping acid. The resultant copolymers were characterized by FTIR, UV-Vis, TEM, X-ray diffraction, cyclic voltammetry and conductivity measurements. The results showed that the copolymers prepared under different aniline and o-methoxyaniline molar ratios displayed an emeraldine salt phase, and the doping degree of copolymers decreased with increasing content of o-methoxyaniline in monomers. The as-prepared copolymers had a high crystallinity and displayed a fibrillar morphology. The copolymer prepared under the molar ratio of 1:1, exhibited a higher electrochemical activity than the others, and its conductivity was 1. 65 S/cm.关键词
固相法合成/共聚物/苯胺/邻甲氧基苯胺Key words
solid-state synthesis/ copolymer/ aniline/ o-methoxyaniline分类
化学化工引用本文复制引用
吐尔逊·阿不都热依木,如仙古丽·加玛力,吐尼沙古丽·阿吾提,司马义·努尔拉,许峰,邵伟伟..固相法合成苯胺与邻甲氧基苯胺共聚物及其性能[J].应用化学,2012,29(10):1117-1122,6.基金项目
国家自然科学基金资助项目(20964004),石油天然气精细化工教育部和自治区重点实验室开放课题(XJDX0908-2009-03) （20964004）
